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Arcade Mode
The game choose 4 characters and goes through 8 stages, the 1st 3 are against random teams of 4 opponents, the 4th is against any 4 of the Mid-Bosses in a team, the 5th and 6th are against random teams of 4 opponents again, the 7th is against Gill and Igniz in a tag team and the 8th is against either Sigma or Magaki in Round 1 and against either Awakened Sigma or Virus Magaki in Round 2.

Capcom Side

 * 1) Ryu
 * 2) Ken Masters
 * 3) Chun-Li
 * 4) Guile
 * 5) Zangief
 * 6) Sakura Kasugano
 * 7) Alex
 * 8) Cammy White
 * 9) Cody Travers
 * 10) Dhalsim
 * 11) Dan Hibiki
 * 12) E.Honda
 * 13) Blanka
 * 14) Balrog
 * 15) Adon
 * 16) Vega
 * 17) Sagat
 * 18) Urien
 * 19) Juri Han
 * 20) Morrigan Aesland
 * 21) Ibuki
 * 22) Sean Matsuda
 * 23) Hugo Andore
 * 24) Demitri Maximoff
 * 25) Guy
 * 26) Megaman
 * 27) Zero
 * 28) Zen (Guest Character from The Rumble Fish)

Mid-Bosses

 * 1) M.Bison (Alongside Rugal, Akuma and Goenitz)
 * 2) Akuma (Alongside Goenitz, M.Bison and Rugal)
 * 3) Pyron (Alongside Amakusa, Jedah and Zankuro)
 * 4) Jedah Domah (Alongside Zankuro, Pyron and Amakusa)

Sub-Boss

 * 1) Gill (Alongside Igniz)

Final Boss

 * 1) Sigma (in Round 1)
 * 2) Awakened Sigma (in Round 2)

SNK Side

 * 1) Kyo Kusanagi
 * 2) Iori Yagami
 * 3) Mai Shiranui
 * 4) Benimaru Nikaido
 * 5) Goro Daimon
 * 6) Yuri Sakazaki
 * K'
 * 1) Leona Heidern
 * 2) Terry Bogard
 * 3) King
 * 4) Joe Higashi
 * 5) Ryo Sakazaki
 * 6) Vice
 * 7) Kim Kaphwan
 * 8) Billy Kane
 * 9) Ryuji Yamazaki
 * 10) Geese Howard
 * 11) Krizalid
 * 12) Ash Crimson
 * 13) Nakoruru
 * 14) Whip
 * 15) Shingo Yabuki
 * 16) Raiden
 * 17) Haohmaru
 * 18) Andy Bogard
 * 19) Marco Rossi
 * 20) Fio
 * 21) Kazuya (Guest Character from Kaiser Knuckle)

Mid-Bosses

 * 1) Rugal Burnstein (Alongside M.Bison, Goenitz and Akuma)
 * 2) Leopold Goenitz (Alongside Akuma, Rugal and M.Bison)
 * 3) Shiro Tokisada Amakusa (Alongside Pyron, Zankuro and Jedah)
 * 4) Zankuro Minazuki (Alongside Jedah, Amakusa and Pyron)

Sub-Boss

 * 1) Igniz (Alongside Gill)

Final Boss

 * 1) Magaki (in Round 1)
 * 2) Virus Magaki (in Round 2)